Sonochemical Reduction of Silver Ions in Nano-Porous Y-Zeolite
Publish place: 06th International Congress on Chemical Engineering
Publish Year: 1388
نوع سند: مقاله کنفرانسی
زبان: English
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ICHEC06_434
تاریخ نمایه سازی: 1 مهر 1388
Abstract:
Silver ions are reduced by 24 kHz ultrasonic waves in ion-exchanged Ag+-Y zeolite. Zeolite is both a good selective catalyst and an excellent support with high surface area that is well known in petrochemical industry. Silver ions are introduced into the nano-porous (1.2nm) zeolite lattice by ionexchange. After the reduction process, silver particles are placed both in the cavities, in nanometric sizes and on the external surfaces of the zeolite. Fast and simple reduction of silver ions in the zeolite, in the lab-scale is important for researchers who work on catalytic uses of metallic silver-zeolite. Several reduction methods have been reported but reduction by ultrasonic waves is a new, simple and sizecontrollable method with a high practical value which doesn't need any complicated facility. In sonochemical process, the collapse of bubbles formed by ultrasonic waves, cause the formation of reducing radicals that consequently reduce the silver ions. It is concluded that the higher the silvercontent, the larger the silver crystals formed on the external surface of zeolite. Also, the addition of 1- propanol to the aqueous reaction solution doesn't cause better reduction. All samples are irradiated under the same ultrasonic conditions. The samples are analyzed by XRD, SEM and EDS.
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Authors
Jafar Talebi
Faculty of Chemical Engineering Amirkabir University of Technology, Tehran, Iran
Rouein Halladj
Faculty of Chemical Engineering Amirkabir University of Technology, Tehran, Iran
Sima Askari
Faculty of Chemical Engineering Amirkabir University of Technology, Tehran, Iran
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