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Using the transient metal-ligand interaction to formation of metallosupramolecular hydrogels: Kinetics' study

عنوان مقاله: Using the transient metal-ligand interaction to formation of metallosupramolecular hydrogels: Kinetics' study
شناسه ملی مقاله: ICHEC06_497
منتشر شده در ششمین کنگره بین المللی مهندسی شیمی در سال 1388
مشخصات نویسندگان مقاله:

Abolfazl Barati - Chemical Engineering Department, Faculty of Engineering, Arak University, Arak, Iran
Nasim Khadij - Chemical Engineering Department, Faculty of Engineering, Arak University, Arak, Iran
Gholamhassan Azimi - Chemistry Department, Faculty of Pure Sciences, Arak University, Arak, Iran

خلاصه مقاله:
Stimuli responsive material was a group of material that notice recently. This material have a unique properties and exhibit dramatic change in their properties to the environmental stimulus such as light, temperature, mechanical stress pH, ionic strength and etc. These groups of materials have a supramolecular structure. Supramolecular structure refer to the molecule that assembly by using non-covalent interaction such as hydrogen bonding, π-π stacking, metal ligand coordination, and Columbic force. Among varied class of this material the use of supramolecular gel were noticed and preparing this gel by using transient metal ligand was investigate. Utilizing metal-ligand binding as the driving force for the self-assembly a series of mechanically-strong metallo-supramolecular hydrogels, which exhibit dramatic reversible responses to a variety of stimuli, including thermal, mechanical and chemical, have been prepared of a transient metal. In this research the acrylamide gel was prepared by using Cr(NO3)3 as metal ligand interaction that cause cross-linking. For investigate the composition of the gel, we use UV spectroscopy. This result shows that the ratio of acrylamide to chromium (III) ion was 6:1 in supramolecular structure.

کلمات کلیدی:
stimuli responsive, supramolecular, acrylamide gel, chromium ion , physical

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/77769/