Effective removal of hexavalent mercury from aqueous solution by modified polymeric nanoadsorbent

Mercury is one of the most toxic metals present in the environment. Adsorption has been proposed among the technologies for mercury adsorbent. The kinetics of adsorption depends on the adsorbent concentration, and the physical and chemical characteristics of adsorbent. In this study we were used a novel adsorbent, magnetite-polyrhodanine core- shell nanoparticles, for removing Hg(II) from aqueous solution. The effect of pH, initial Hg(II) concentration, initial adsorbent concentration and contact time on the efficiency of Hg(II) removal were investigated systematically by batch experiments. The maximum adsorption capacity was obtained 29.14 mg g-1 at PH=6.5 and 25°C with 10 g L-1 nano adsorbent. The kinetic data of adsorption of Hg(II) ion on the synthesized adsorbent were best described by a pseudo- second- order equation, indicating their chemical adsorption. The Freundlich, Langmuir and Temkin isotherms were used to modeling of mercury adsorption on Hg(II) in aqueous medium which modeled best by the Freundlich isotherm is whole concentration rage.

Keywords:

Adsorption , Core-shell polymer , Mercury , Morphology , Nanocomposite