The Synthesis and characterization of 2-methoxy-4-(2H-tetrazol-5-yl)phenol
عنوان مقاله: The Synthesis and characterization of 2-methoxy-4-(2H-tetrazol-5-yl)phenol
شناسه ملی مقاله: MIAUCHEMISTRY01_072
منتشر شده در همایش منطقه ای شیمی در سال 1389
شناسه ملی مقاله: MIAUCHEMISTRY01_072
منتشر شده در همایش منطقه ای شیمی در سال 1389
مشخصات نویسندگان مقاله:
Ladan Edjlali - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
M Babazadeh - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
A Zeinali - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
Y Soleymani - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
خلاصه مقاله:
Ladan Edjlali - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
M Babazadeh - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
A Zeinali - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
Y Soleymani - Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
Since the 1980s, the growth of tetrazole chemistry has continued unabated due to its popular functionality with a wide range of pplications . Tetrazoles have found use in pharmaceuticals, specialty eplosives, photography and information recording ystems , not to mention as precursors to a variety of nitrogen containing heterocycles. It has long been known that simpleh eating of azide salt with nitrile in a solution produces the corresponding tetrazole [1]. In this research work, we synthesized some new compounds of alkyl tetrazoles. Therefore, 4-hydroxy-3-methoxybenzaldehyd (1) in reaction with NH2OH was converted to 4-hydroxy-3-methoxybenzaldehyde oxime (2). The obtained compound was dehydrated by acetic anhydride to give 4-hydroxy-3-methoxybenzonitrile (3). Then, 2-methoxy-4-(2H-tetrazol-5-yl)phenol(4) was prepared by [2+3] cycloaddition reaction between (3) and NaN3.The structure of all the synthesized compounds were characterized and confirmed by FT-IR and NMR spectroscopy techniques.
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/828942/