RuCl2(p-cymene)]2 complex immobilized on reduced graphene oxide for the synthesis of carboxylic acids from alcohol dehydrogenation
Publish place: 20th Iranian Chemical Congress
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
IRANCC20_159
تاریخ نمایه سازی: 28 اردیبهشت 1398
Abstract:
For developing high performance of graphene-based nanocatalysts, dispersibility of graphene sheets in matrices and interfacial interaction are challenging due to the strong tendency of agglomeration and surface inertia of graphene. Here we report an efficient way to functionalize graphene nanosheets with 1,4-Diaminobenzene on their surfaces, to attain the functionalized graphene by diazonium treatment following reduction of graphene oxide with hydrazine hydrate. In the following amine-grafted reduced geraphene oxide reacted with 2,4,6-trichloro-1,3,5-triazine and sodium ethanediamine respectively. Finally ruthenium complex RuCl2(p-cymene)]2 immobilized on modified reduced geraphene oxide. Prepared catalyst applied for the synthesis of carboxylic acids from alcohol dehydrogenation for this purpose, catalytic assays were performed in a round bottom flask, using 1 equivalent of alcohol, 1equivalent of cesium carbonate, catalyst and 10 mL of solvent for 24 hours at 100 °C. Yields and conversions were determined by GC analysis.
Authors
Mohaddeseh Shahabi Nejad
Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran
Neda Seyedi
Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran,Department of Chemistry, Faculty of Science, University of Jiroft, Jiroft,Iran
Hassan Sheibani
Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran