Graphene Oxide‐Supported Palladium Complex: Synthesis, Characterization and Application in Cross-Coupling Reactions

Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:

IRANCC20_439

تاریخ نمایه سازی: 28 اردیبهشت 1398

Abstract:

Graphene oxide (GO) possesses a number of advantageous properties, such as twodimensional planar structure, large surface area, chemical and mechanical stability,superb conductivity and good biocompatibility [1]. Graphene oxide as a substrate for a variety of chemical transformations has been reported. The transition-metal-catalyzed carbon-carbon and carbon-heteroatom bond-forming reactions are important fundamental transformations in synthetic chemistry [2]. Inspiring from recent developments in the field of nanocatalyst [3], herein, we report preparation and characterization of GO- supported palladium complex with terpyridinbased ligands which has also been applied as an effective nanocatalyst for the C−C, C−N, C-S and C-O bond formations via cross-coupling reactions of aryl halides. In addition, the catalyst can be reused up to four times without losing much of its activity

Authors

Kiumars Bahrami

Department of Organic Chemistry, Faculty of Chemistry, Razi University, Kermanshah, Iran,Nanoscience and Nanotechnology Research Center (NNRC), Razi University, Kermanshah,Iran;

Homa Targhan

Department of Organic Chemistry, Faculty of Chemistry, Razi University, Kermanshah, Iran