CIVILICA We Respect the Science
(ناشر تخصصی کنفرانسهای کشور / شماره مجوز انتشارات از وزارت فرهنگ و ارشاد اسلامی: ۸۹۷۱)

Synthesis and Spectral Study of a zinc(lI) Complex with NN O-Donor Ligand

عنوان مقاله: Synthesis and Spectral Study of a zinc(lI) Complex with NN O-Donor Ligand
شناسه ملی مقاله: IRANCC20_490
منتشر شده در بیستمین کنگره شیمی ایران در سال 1397
مشخصات نویسندگان مقاله:

Zahra Mardani - Chemistry Department, Urmia University, ۵۷۵۶۱۵-۱۸۱۸ Urmia, I. R. Iran
Reza Kazem Shoar - Chemistry Department, Urmia University, ۵۷۵۶۱۵-۱۸۱۸ Urmia, I. R. Iran
Keyvan Moeini - Chemistry Department, Payame Noor University, ۱۹۳۹۵-۴۶۹۷ Tehran, I. R. Iran

خلاصه مقاله:
In this work, 2-(2-(2-hydroxyethylamino)ethylamino)cyclohexanol (L) was prepared in solvent by ring opening of epoxycyclohexane with 2-(2-aminoethylamino)ethanol andthen its complex with zinc(II), [Zn(L)Cl2] were prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy and single-crystal X-Ray diffraction. The spectroscopies data revealed that the ligand acts as NN O-donor mode toward zinc atom and in agree with the structural analysis result. The X-ray analysis showed thatthe zinc atom has distorted trigonal bipyramidal geometry. In the crystal network of the complex there are intermolecular N–H···Cl, O–H···Cl and O–H···O hydrogenbonds, extending the crystal network in three directions.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/851120/