Effect of CH3NH3I Concentration on Efficieny of Mesoporous Methylammonium Lead Iodide Perovskite Solar Cell
Publish place: 20th Iranian Chemical Congress
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
IRANCC20_493
تاریخ نمایه سازی: 28 اردیبهشت 1398
Abstract:
Perovskite solar cells (PSCs) based on organometal halide have emerged as excellent light absorbers in solar cells with a rapid evolution in efficiency from 3.8% in 2009 to 22.1% in 2016 [1,2]. The remarkable achievement in power conversion efficiency (PCE) of perovskite solar cells is attributed to the unique properties of these materials, such as appropriate direct band gap, high absorption coefficient, long charge diffusion lengths, excellent carrier mobility and solution-based fabrication method [3-4].In this work, we investigated the effects of CH3NH3I concentration in mesoporous perovskite solar cells prepared using a two-step solution deposition method. Photovoltaic performance of PSCs is found to strongly depends on the concentration of CH3NH3I. Under simulated one-sun illumination, average efficiencies of 6.1% (s.d.±0.31), 9.96% (s.d.±0.67) and 2.4% (s.d.±0. 4) are obtained from solutions of CH3NH3I with concentrations of 0.038 M, 0.044 M and 0.063 M, respectively. we achieved the best efficiency of 11.29% with a photocurrent density of 20.22 mA.cm–2, open-circuit photovoltage of 0.814 V and fill factor of 0.66.
Authors
Effat Moshfeghi
Sonochemical Research Center
Mohammad H. Entezari
Sonochemical Research Center, Environmental Chemistry Research Center, Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad,۹۱۷۷۹ Mashhad, Iran