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Study of volumetric and electromagnetic properties of binary and ternary mixtures of {2-Propanol (1) + 1, 3-Diaminopropane (2) + 2, 5- Dimethoxytetrahydrofuran (3)} at (298.15- 328.15) K at 81.5 kPa-Prediction with geometrical models

عنوان مقاله: Study of volumetric and electromagnetic properties of binary and ternary mixtures of {2-Propanol (1) + 1, 3-Diaminopropane (2) + 2, 5- Dimethoxytetrahydrofuran (3)} at (298.15- 328.15) K at 81.5 kPa-Prediction with geometrical models
شناسه ملی مقاله: JR_CIC-1-2_005
منتشر شده در شماره 2 دوره 1 فصل در سال 1397
مشخصات نویسندگان مقاله:

Mahdi Jafarnejad - Department of Physical chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
Farnoosh Panahi - Department of Physical chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
Hossein Iloukhani - Department of Physical chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
Khatereh Khanlarzadeh - Department of Physical chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

خلاصه مقاله:
The densities, ρ and refractive index, nD of mixtures consisting of 2-Propanol, 1, 3-Diaminopropane, and 2, 5-Dimethoxytetrahydrofuran have been measured at different temperatures. VEm, ṼEm,i,  ΔnD , αE and (ǝHEm / ǝP )T,x for binary and VEm and ΔnD for ternary mixtures were derived. VEm and ΔnD for binary mixtures were correlated with the Redlich‒Kister equation and for ternary mixtures were correlated with several equations. Prediction geometrical solution models were used to predict VEm, ΔnD of ternary mixtures and standard deviation for their fitting was reported. Positive deviation from ideal state were recorded for VEm in mixture of 1, 3-Diaminopropane + 2, 5-Dimethoxytetrahydrofuran and 2-Propanol + 2, 5-Dimethoxytetra-hydrofuran mixtures. However in mixture of 2-Propanol and 1, 3-Diaminopropane negative deviation in the high composition of 1, 3-Diaminopropane varies to positive in the dominated mole fraction of alcohol which was analyzed to interpret the molecular interactions.

کلمات کلیدی:
Ternary mixtures, Volumetric properties, Refractive index, Molecular interactions, Prediction models

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/857113/