Synthesis and characterization of carbon quantum dots by electrochemical method using ethanolamine and ethanol
عنوان مقاله: Synthesis and characterization of carbon quantum dots by electrochemical method using ethanolamine and ethanol
شناسه ملی مقاله: NICEC16_660
منتشر شده در شانزدهمین کنگره ملی مهندسی شیمی ایران در سال 1397
شناسه ملی مقاله: NICEC16_660
منتشر شده در شانزدهمین کنگره ملی مهندسی شیمی ایران در سال 1397
مشخصات نویسندگان مقاله:
Ghazaleh Mirakhori - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
Shohreh Fatemi - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
Afsaneh Mozdbar - Fouman Faculty of Engineering, College of Engineering, University of Tehran, Iran
Fatemeh Sadat Talatori - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
خلاصه مقاله:
Ghazaleh Mirakhori - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
Shohreh Fatemi - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
Afsaneh Mozdbar - Fouman Faculty of Engineering, College of Engineering, University of Tehran, Iran
Fatemeh Sadat Talatori - School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
Carbon Quantum Dots (CQDs) are a new class of carbon-based nanomaterials that have attracted researcher’s attention because of their photovotaic properties In this work, CQDs were synthesized by the electrochemical method under DC voltage of 60 V, during 8 h using ethanol or ethanolamine as the electrolyte material and the effect of temperature was studied in the range of 25 to 120°C. Synthesized CQDs were characterized by using TEM and FTIR analysis, and, optical properties were investigated by UV-Visible Spectroscopy. The results revealed the absorption edge of synthesized CQDs had red-shifted absorption from 348 to 389 nm using ethanol and ethanolamine respectively, at 70°C synthesis temperature. Application of ethanolamine could produce CQDs doped with nitrogen and the TEM analysis results showed that particles were formed with two different sizes distribution around 5-10 and 20-25 nm. Increasing temperature caused a higher rate of formation and resulted in more absorption edge red-shift of the formed CQDs.
کلمات کلیدی: carbon quantum dots, synthesis, electrochemical method, photoluminescence, nanoparticles
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/860323/