Electrocatalytic determination of ascorbic acid using Cu(II) doped zeolite modified electrode

A new method is developed for the catalytic oxidation of ascorbic acid at graphite zeolite-modified electrode, doped with copper(II) (Cu2+A/ZCME). Copper(II) exchanged in zeolite type A acts as catalyst to oxidize ascorbic acid. The modified electrode lowered the overpotential of the reaction by ~400 mV. First, the electrochemical behavior of copper(II), incorporated in the zeolite type A modified electrode, was studied. The results illustrate that diffusion can control the copper(II)/copper(0) redox process at the Cu2+A/ZCME. Then, the behavior of electrocatalytic oxidation reaction for ascorbic acid was researched. The electrode was employed to study electrocatalytic oxidation of ascorbic acid, using cyclic voltammetry and chronoamperometry as diagnostic techniques. The diffusion coefficient of ascorbic acid was equal to 1.028 ×10-5 cm2s-1. A linear calibration graph was obtained over the ascorbic acid with a concentration range of 0.003–6.00 mmol L-1. The detection limit (DL) of ascorbic acid was estimated as 2.76×10-7 mol L-1. The relative standard deviations of 10 replicate measurements (performed on a single electrode at several ascorbic acid concentrations between 3.0 to 200 μmol L-1) were measured between 1.0 to 2.4% .

Keywords:

Electrocatalytic oxidation , Modified electrode , Cu2+A/ZCME , Ascorbic acid