Investigation of the Electrochemical behavior of 4-Morpholinoaniline in the presence of α-oxoketene N,N-acetals
Publish place: The Regional Chemistry Conference
Publish Year: 1389
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
MIAUCHEMISTRY01_157
تاریخ نمایه سازی: 18 اسفند 1397
Abstract:
The electrochemical oxidation of 4-Morpholinoaniline in the presence of α-oxoketene N,N-acetals was studied by cyclic voltammetry and controlled potential coulometry on platinum electrode in ethanol/acetonitrile (1:4) as solvent. The results show a two-step oxidation and a two-step reduction in reverse scan as counterparts. Bulk electrolysis of 4-Morpholinoaniline in constant potential demonstrated a 2 electron oxidation process.Voltammetry and coulometry investigations of oxidation of 4-Morpholinoaniline in the presence of α-oxoketene N,N-acetals confirm attack of nucleophile to oxidized form of 4-Morpholinoaniline, to form a new product via an EC electrochemical mechanism.was performed in these solvents and the progress of the oxidation reaction as a function of time was monitored through cyclic voltammetry.
Authors
A. Niazi
Department of chemistry, Faculty of Science, Islamic Azad University, Arak Branch, Arak, Iran- Young Researchers Club, Islamic Azad University, Arak Branch, Arak, Iran
V. Mahboobi
Department of chemistry, Faculty of Science, Islamic Azad University, Arak Branch, Arak, Iran- Young Researchers Club, Islamic Azad University, Arak Branch, Arak, Iran