Adsorption Study of Pb(II) Ions on the Blast Furnace Slag (BFS) from Aqueous Solution

In this work, blast furnace slag (BFS) was used as an adsorbent material for the removal of Pb(II) ions in solution in batch mode. The physico-chemical analyzes used indicated that the BFS is essentially composed of silica, lime, and alumina. Its specific surface area corresponds to ۲۷۵.۸m۲/g and its PZC is around ۳.۸. The adsorption study indicated that the maximum amount of Pb(II) adsorbed under optimum conditions (agitation speed (Vag): ۱۵۰rpm; pH: ۵.۴; particle size (Øs): ۳۰۰µm, T: ۲۰°C) is ۳۴.۲۶mg/g after ۵۰ minutes of agitation, and adsorption yield is best for feeble initial concentrations. The most appropriate isothermal model was that of Langmuir, and the adsorption speed was better characterized by the pseudo-second order kinetic model. The adsorption mechanism revealed that internal diffusion is not the only mechanism that controls the adsorption process; there is also external diffusion, which contributes enormously in the transfer of Pb(II) from solution to adsorbent. Thermodynamic study indicated that the Pb(II) adsorption on the blast furnace slag (BFS) was spontaneous, exothermic, and that the adsorbed Pb(II) is more ordered at the surface of the adsorbent. Finally, we estimate that BFS is a superb adsorbent for water containing Pb(II).

Keywords:

Adsorption , Slag , Pb(II) , Kinetics , depollution