Thermostable Polarizing Film on the Basis of Poly (vinyl alcohol) and New Dichroic Synthesized Azo Dye for Optical Applications: Theoretical and Experimental Investigations
Publish place: Chemical Methodologies، Vol: 1، Issue: 2
Publish Year: 1396
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_CHM-1-2_006
تاریخ نمایه سازی: 12 شهریور 1402
Abstract:
Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of the new dichroic mono azo dye: Sodium (E)-۵-((۴-carboxylatophenyl)diazenyl)-۲-hydroxybenzoate (S) (trans isomer) was carried out using B۳LYP methods with ۶-۳۱۱+G* basis set. After calculations, the new mono azo dye was synthesized. UV, FT-IR and ۱H NMR spectra of the compound S are reported. The electronic spectrum of the mono azo dye S was also carried out in the water solution. Interpretation of absorption strips in UV region of spectrum was also reported. On the basis of the polyvinyl alcohol (PVA) and the new dichroic synthesized azo dye thermostable polarizer film absorbing in the UV region of spectrum (λmax=۳۸۸ nm) with effect of polarization (PE) in the absorption maximum ۹۷% was developed. The main spectral-polarization parameters (transmittance, optical density) of stretched PVA-films were measured and discussed.It was also established that oriented colored PVA-films is phenomenon of anisotropy of thermal conductivity (l|| / l^). Thermal conductivity in the direction of orientation (l||) is higher than in the direction perpendicular to the orientations (l^). The developed thermostable polarizer film was used in polarizing microscopes, circular polarizers, magnetometers, spectropolarimeters and electrical signals sensors.
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Authors
Siyamak Shahab
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus,۱۳ Surganov Str., Minsk ۲۲۰۰۷۲
Liudmila Filippovich
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus,۱۳ Surganov Str., Minsk ۲۲۰۰۷۲
Masoome Sheikhi
Young Researchers and Elite Club, Gorgan Branch, Islamic Azad University, Gorgan, Iran
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