Photochemical, Solvatochromic, Electrochromic and Kinetic Investigation of New Synthesized Bicyclic Aziridines with Chalcone Moieties
Publish place: Organic Chemistry Research، Vol: 3، Issue: 1
Publish Year: 1396
نوع سند: مقاله ژورنالی
زبان: English
View: 123
This Paper With 9 Page And PDF Format Ready To Download
- Certificate
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
JR_ORGC-3-1_011
تاریخ نمایه سازی: 3 مهر 1402
Abstract:
Bicyclic aziridines show exclusive photochromic behavior. Here, we summarize the results of optical and electrochemical properties, such as photochemical, solvatochromic, electrochromic andkinetic behavior of bicyclic aziridines linked to chalcone moieties. The photochromic process for conversion of closed photoisomers to open photoisomers for compounds ۱-۱۰ followed zero-order kinetics. For considering the solvatochromic properties of compounds ۱,۳,۵,۷ and ۹, photochromic properties of these compounds in different solvents were investigated and the negative solvatochromism were observed. The redox behavior of several derivatives of bicyclic aziridines by cyclic voltammetry was examined for compounds ۱,۳,۵ and ۶, and irreversible oxidation was observed.
Keywords:
Authors
Nosratollah Mahmoodi
Department of Chemistry, Faculty of Science, University of Guilan, P.O. Box: ۴۱۳۳۵-۱۹۱۴, Rasht, Iran
Tayebeh Besharati-Seidani
Department of Chemistry, Faculty of Science, University of Guilan, P.O. Box: ۴۱۳۳۵-۱۹۱۴, Rasht, Iran
A. Aliakbar
Department of Chemistry, Faculty of Science, University of Guilan, P.O. Box: ۴۱۳۳۵-۱۹۱۴, Rasht, Iran
B. Ghalami Choobar
Department of Chemistry, Faculty of Science, University of Guilan, P.O. Box: ۴۱۳۳۵-۱۹۱۴, Rasht, Iran