Formation of Ni-P Nanostructures by Electrochemical Deposition Method and Evaluation of Electrocatalytic Ectivity for OER Reaction
Publish Year: 1399
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_ICAC-10-38_006
تاریخ نمایه سازی: 5 آذر 1402
Abstract:
It is important to produce cost-effective electrocatalysts that can produce hydrogen at a lower cost and higher purity. In this study, nanostructure Ni-P electrocatalysts were generated by cyclic voltammetry electrochemical deposition method on copper sheet and its electrocatalytic activity was investigated for oxygen evolution reactions. FESEM were used for microstructural investigations and electrochemical tests were used to study the electrocatalytic behavior. The results of this study showed that the number of coating cycles is effective on microstructural and coating morphology and with increasing the number of coating cycles from ۱۵ to ۲۵ and then up to ۴۰ nanostructured surface cycles are almost eliminated and flat surface is created. The results of electrocatalytic activity analysis showed that by increasing the number of coating cycles the electrocatalytic behavior is improved first and then by further increase in the number of cycles the activity decreases and the best electrocatalytic activity of the sample created in the number of cycles. ۲۵, which requires an overpotential of ۲۳۰ mV to produce a current density of ۱۰ mA.cm-۲ due to improved surface active area and improvement of intrinsic electrocatalytic activity. OER reactions also showed that the electrode produced showed excellent behavior compared to other electrodes reported in references
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Authors
محمود حاجی صفری
دانشگاه آزاد اسلامی یزد
امیرحسین سلطانی
دانشگاه آزاد اسلامی یزد