A new kinetic models analysis for CO adsorption on palladium zeolite nanostructure by roll-coating technique
Publish Year: 1399
نوع سند: مقاله ژورنالی
زبان: English
View: 100
This Paper With 16 Page And PDF Format Ready To Download
- Certificate
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
JR_AMECJ-3-2_005
تاریخ نمایه سازی: 14 آذر 1402
Abstract:
The aim of this article was the fabrication of zeolite@Pd/Al۲O۳
nanostructure through roll-coating technique for CO gas adsorption
from air. Transmission electron microscopy (TEM), field-emission
scanning electron microscopy (FESEM), X-ray diffraction (XRD),
and energy-dispersive x-ray spectroscopy (EDX) were performed to
investigate the morphological, structural, and elemental properties
of zeolite@Pd/Al۲O۳ adsorbent. A continues carbon monoxide gas
analyzer KIGAZ ۲۱۰ was applied for analyzing of CO gas adsorption
on as-present adsorbent in an experimental set-up. The adsorption
capacity at equilibrium time for CO molecules was studied by
zeolite@Pd/Al۲O۳ adsorbent. The Elovich, Avrami, and Fractional
power kinetic models were used for this study. The equal value of
experimental and theoretical adsorption capacity at equilibrium time
as well as the unit value of regression coefficient was indicated that the
Avrami kinetic model was the suitable model to describe CO removal
from air through zeolite@Pd/Al۲O۳ nanostructure. The results showed
us, the CO molecules were efficiently removed by catalytic zeolite
adsorbent more than ۹۵% from air at optimized conditions.
Keywords:
Carbon monoxide (CO) , Toxic gas analysis , Adsorption , Alumina palladium zeolite composite films , Kinetic models
Authors
Nastaran Mozaffari
Department of Environmental Engineering, Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran
Alireza Haji Seyed Mirzahosseini
Department of Environmental Engineering, Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran
Niloofar Mozaffari
Department of Physics, Faculty of Sciences, Science and Research Branch, Islamic Azad University, Tehran, Iran