Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods
Publish place: Scientific Journal of Review (SJR)، Vol: 6، Issue: 7
Publish Year: 1396
نوع سند: مقاله ژورنالی
زبان: English
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JR_SJR-6-7_001
تاریخ نمایه سازی: 7 اسفند 1402
Abstract:
Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C۲H۵COO (CH۲PPh۳Br)] and its copper (II) complex [C۲H۵COO (CH۲PP۳Br)] [Cu۲Cl۶] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na۲ [Cu۲Cl۶]. Then, using spectroscopic methods, preparation of these compounds was investigated.Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C۲H۵COO (CH۲PPh۳Br)] and its copper (II) complex [C۲H۵COO (CH۲PP۳Br)] [Cu۲Cl۶] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na۲ [Cu۲Cl۶]. Then, using spectroscopic methods, preparation of these compounds was investigated.
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Authors
Ali Naghipour
Department of Chemistry, Faculty of Science, Ilam University, Iran
Abozar Bastami
MA Graduate in Inorganic Chemistry, Payam Noor University of Hamadan, Iran, Islamic Republic of
Amir Hossein Ezati
BSc in Chemical Engineering, Amir Kabir University of Technology, Tehran, Iran, Islamic Republic of
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