Pigment-Extender Effect of Umunze Clay on Screeding Paint

Publish Year: 1403
نوع سند: مقاله ژورنالی
زبان: Persian
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شناسه ملی سند علمی:

JR_AJCS-7-5_004

تاریخ نمایه سازی: 27 خرداد 1403

Abstract:

The surface coating potentials of indigenous Nigerian clay from Umunze, Orumba South Local Government Area in Anambra state were assessed in screeding paints as part of the effort to provide sustainable materials for the coating industries. The clay samples were washed, sedimented, dried, grinded, and sieved to ۸۰ μm, and analyzed using Energy Dispersive X-ray Fluorescence, X-ray diffraction spectrometry, and scanning electron microscope. The EDXRF results shows a high percentage of Nibioum (Nb), Silica Oxide (SiO۲), and Iron (III) Oxide (Fe۲O۳) with ۱۶.۸۰%, ۱۵.۵۸%, and ۶.۶۰% respectively. Other chemical components like Lead (Pb), Barium (Ba), Zinc (Zn), Nickel (Ni), and Gallium (Ga) were present in very small quantities in the clay gotten from Umunze, meaning that the presence of these metals is too insignificant to cause damages to humans and the environment. Meanwhile, XRD shows very high percentage of Aluminum (Al۲) and Silica (SiO۲) in Umunze clay. This indicated that the crystalline structure of the uncalcined clay obtained from Umunze is kaolinite, with chemical formula given as Al۲Si۲O۹. The surface morphology presented the clay particles to be clogged, thus showing that the umunze clay is desired for multiple clay purposes. The formulated screeding paint from the calcined clay of ۷۵۰ °C gave a better paint than the ۴۵۰ °C via these physical properties of parameters mentioned below. The ۷۵۰ °C calcined screeding paint has its refractive index determined at ۲.۷۱ (PL= ۱.۵-۹), viscosity was determined at ۲۰۳۹.۸ (PL= ۲۰۰۰-۳۰۰۰), and durability was determined at ۷۰% (PL=۶۸- ۹۸ %) and thereby, making it a better substitution as paint pigment-extender than that of ۴۵۰ °C calcined screeding paint. The work revealed a better temperature performance of the sample, such that the produced sample can withstand temperature up to ۳۲۰ °C before it will start deforming. Hence the clay can be used for ceramics.

Authors

Pauline Chris-Okafor

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Joy N. Nwando

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Ozioma J. Anekwe

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Blessing I. Tabugbo

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Precious O. Emole

Department of Chemistry, Abia State University, Uturu, Abia State, Nigeria

Chinasa Okpalaunegbu

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Millicent Adaobi Nwokolo

Departmennt of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Anambra State, Nigeria

Rilwan Usman

Department of Physics, Faculty of Natural and Applied Sciences, Nigerian Army University, P.O.Box ۱۵۰۰ Biu, Borno State, Nigeria

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