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Fast Adsorption for Diclofenac Sodium Based on UiO-۶۶-NH-EDTA-Fe

Publish place: Iranian Journal of Chemistry and Chemical Engineering، Vol: 42، Issue: 12
Publish Year: 1402
نوع سند: مقاله ژورنالی
زبان: English
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لینک ثابت به این Paper:
https://civilica.com/doc/2281864

شناسه ملی سند علمی:

JR_IJCCE-42-12_004

تاریخ نمایه سازی: 17 خرداد 1404

Abstract:

It is meaningful to develop rapid adsorption materials for organic pollutants. Metal-Organic Frameworks (MOFs) are efficient adsorbents for organic contaminants. The UiO-۶۶-NH-EDTA-Fe was synthesized with the precursor of UiO-۶۶-NH۲. The UiO-۶۶-NH-EDTA-Fe was characterized with XRD, XPS, FT-IR spectra, Brunauer–Emmett–Teller, and TGA. The influence of pH, temperature, and the adsorbent dosage on adsorption performance was investigated. The maximum adsorption capacity of UiO-۶۶-NH-EDTA-Fe was ۶۶۸.۷ mg/g for DS (diclofenac sodium). Moreover, the equilibrium time only required ۵ min, which was shorter than the recently reported works. The DS adsorption behavior on UiO-۶۶-NH-EDTA-Fe was very close to the pseudo-second-order kinetics models. The Langmuir model was more suitable for illustrating the adsorption isotherms of DS adsorption. The presence of NaCl and Na۲SO۴ could influence the adsorption performance of DS. In addition, UiO-۶۶-NH-EDTA-Fe can be reused no fewer than ۳ times. Finally, the potential of UiO-۶۶-NH-EDTA-Fe was considered as a novel adsorbent for the removal of Diclofenac Sodium (DS).

Keywords:

UiO-۶۶-NH-EDTA-Fe , Adsorption , Diclofenac sodium , MOFs

Authors

Zhenliang Li

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Zhongrui Zhang

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Shuye Li

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Xuerui Liu

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Shaoying Yuan

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Enke Feng

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

Zhiqiang Wu

College of Chemistry and Chemical Engineering, Ningxia Normal University, Guyuan, ۷۵۶۰۰۰, P.R. CHINA

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