Solar Photocatalytic Degradation of Diclofenac by N-Doped TiO۲ Nanoparticles Synthesized by Ultrasound

Anatase N-doped TiO۲ nanoparticles were synthesized using ultrasound at low frequency and room temperature. The samples characterized by techniques including XRD, TEM, HRTEM, FT-IR, XPS, and UV–Vis spectroscopy. XPS indicated the existence of nitrogen as an anion dopant within the TiO۲ lattice. The solar photocatalytic activity of N-doped TiO۲ studied for the degradation and complete mineralization of Diclofenac (DCF). The results showed that the catalytic activity of the nanoparticles related to the operating conditions in the synthesis such as temperature and time of sonication. DCF degradation followed the pseudo-first-order kinetics model under different conditions. Results showed that photogenerated electrons on the catalyst surface played an important role in the mechanism of photocatalytic degradation of DCF. It also confirmed that in the presence of oxygen, the formation of oxidative species such as singlet oxygen and superoxide radicals had major roles in the degradation of DCF.

Keywords:

Ultrasound , N-doped TiO۲ nanoparticles , Photocatalytic degradation , Diclofenac , Mineralization