Pervaporation separation of water/isopropanol mixtures with poly(vinyl alcohol) membranes crosslinked with fumaric acid :Effect of crosslinking time on the mechanical and separation properties
Publish place: 07th International Congress on Chemical Engineering
Publish Year: 1390
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ICHEC07_134
تاریخ نمایه سازی: 25 فروردین 1394
Abstract:
Cross-linked Poly (vinyl alcohol) membranes were prepared by using fumaric acid as the crosslinking agent and the effects of cross-linking time on the mechanical properties and membraneperformance in terms of flux and selectivity were investigated. The crosslinking time varied between 10min to 60min .The characteristics of the membranes were determined by Fourier transform infrared (FT-IR) and tensile tests. FT-IR results proved that by increasing the crosslinkingtime more ester groups were formed in the cross-linked membranes. Also, An initial increase was seen for yield stress of the membrane cross-linked for 10 minutes, but further increase in the cross-linking time caused a reduction in this parameter. The effect of feedtemperature and concentration on pervaporation dehydration of water/isopropanol(IPA) were studied for all of the developed membranes.Poly(vinyl alcohol) membranes were crosslinked for60minutes showed the highest selectivity of 1492. The temperature dependency of flux was investigated by using Arrhenius relationship and activation energy calculated for total permeation flux(Ep), water flux(Epw) and isopropanol(EpIPA). The lower value of Epw in comparison with EpIPA indicates that the developed membranes have excellent dehydration performance.
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Authors
Maryam Heydari
Department of Chemical Engineering, Isfahan University of Technology,Iran
Ahmad Moheb
Department of Chemical Engineering, Isfahan University of Technology,Iran
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