Walnut shell-assisted synthesis of mesoporous magnesia
Publish place: National Congress on Chemistry and nano-chemistry, from research to national development
Publish Year: 1396
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
MRSS01_005
تاریخ نمایه سازی: 29 فروردین 1397
Abstract:
In the present study high surface area amorphous magnesia was synthesized using walnut shell as a template. This green, simple and useful synthetic protocol was based on the precipitation of magnesium nitrate on biomass in an aqueous phase followed by calcination. Materials were characterized using X -ray diffraction, scanning electron microscopy and N2 adsorption/desorption porosimetry and the results exhibited high surface area for magnesium oxide. Furthermore, the pore size and surface area of these mesoporous materials can be adjusted by varying the biomass/magnesium nitrate ratio. Additionally, magnesium oxide was studied as the support of palladium nanoparticles for the aerobic oxidation of alcohols. We have found that resulting Pd-loaded material act as an effective catalytic system for the aerobic oxidation of benzylic and aliphatic alcohols. The catalyst can be recovered and reused three times without loss of activity.
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Authors
Mojtaba Abedi
Nanotechnology Research Center, Urmia University, Urmia ۵۷۱۵۴, Iran
Asghar Zamani
Nanotechnology Research Center, Urmia University, Urmia ۵۷۱۵۴, Iran
Ahmad Poursattar Marjani
Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia ۵۷۱۵۴
Mahmoud Ghasemi
Nanotechnology Research Institute, Urmia University, Urmia, Ira