Microwave assisted green synthesis of α,ά- bis(substituted-benzylidene)alkanones catalyzed by NbCl5
Publish place: Iranian Chemical Communication، Vol: 3، Issue: 2
Publish Year: 1394
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_ICC-3-2_002
تاریخ نمایه سازی: 1 مرداد 1397
Abstract:
The catalytic application of NbCl5 as a heterogeneous catalyst was explored for the synthesis ofα, ά- bis (substituted- benzylidene) alkanones under solvent-free conditions. The results showedthat aldehydes bearing electron–releasing substituents on phenyl-ring favored the formation ofproduct in good to excellent yields with reaction times ranging between 3 and 7 min. In addition,furfural, cinamaldehyde, thiophene-2-carbaldehyde and 5-methylthiophene-2-carbaldehyde wereinvestigated in aldol reaction, and the results showed excellent yields.The microwave irradiationgave excellent yields at lower reaction time compared to room temperature (1.5-5 h) and thermalconditions (80 0C, 15-45 min). The microwave irradiation afforded selectively cross aldol products.
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Authors
Ali Allahresani
Department of Chemistry, College of Sciences, University of Birjand, P.O. BOX ۹۷۱۷۵-۶۱۵, Birjand, Iran
Mohammad Ali Nasseri
Department of Chemistry, College of Sciences, University of Birjand, P.O. BOX ۹۷۱۷۵-۶۱۵, Birjand, Iran
Batol Zakeri Nasab
Department of Chemistry, College of Sciences, University of Birjand, P.O. BOX ۹۷۱۷۵-۶۱۵, Birjand, Iran