Synthesis, spectral and theoretical Studies of some new complexes of mercury with a new asymmetric bidentate Schiff base ligand
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
IRCCE05_107
تاریخ نمایه سازی: 17 مرداد 1398
Abstract:
Synthesis, identification and theoretical studies of a new asymmetric bidentate Schiff base 2-(4-chloro- (benzylideneimine) thiophenol (L) and its complexes with general formula HgL(Ph), HgL2 and HgLX2 (X= Clˉ, Brˉ, Iˉ) were described. Authenticity of the ligand and its complexes has been established by microanalyses, FT-IR, UV-Vis, 1H NMR, 13 C NMR spectra and by molar conductivity measurements, the complexes are non-electrolytes in DMF. The electronic spectra of the complexes were recorded in DMF solution. 1H and 13C NMR spectra been studied in CDCl3. The HgLX2, PhHgL and HgL2 complexes have suggested to be pseudo-tetrahedral geometry.
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Authors
m razzaghi
Department of Chemistry, Yasouj University, Yasouj, ۷۵۹۱۸۷۴۸۳۱ Iran
m Montazerozohori
Department of Chemistry, Yasouj University, Yasouj, ۷۵۹۱۸۷۴۸۳۱ Iran
z Akbari
Department of Chemistry, Yasouj University, Yasouj, ۷۵۹۱۸۷۴۸۳۱ Iran
s Joohari
Department of basic sciences, Yasooj Branch, Islamic azad University, Yasooj, Iran.