A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation

Shrinivas L. Nakkalwar; Hanmant M. Kasralikar; Nitish S. Kaminwar; Shivaji B. Patwari

A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation

Publish place: Asian Journal of Green Chmistry، Vol: 4، Issue: 2

Publish Year: 1399

Type: Journal paper

Language: English

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https://civilica.com/doc/1032141

Document National Code:

JR_AJGC-4-2_004

Index date: 22 July 2020

A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation abstract

A novel and green synthesis of 1-phenyl isoquinoline derivatives has been developed using [Ru(p-cymene)Cl2]2, as a homogeneous recyclable catalyst, with Cu(OAc)2 and AgSbF6 as oxidant and additive respectively, in PEG-400 biodegradable and green solvent via C-H/N-N functionalization of 1-(diphenylmethylene) hydrazine and aryl substituted acetylene. This protocol gives a simple extraction procedure, biodegradable and green solvent, high atom economy, reusable catalytic system and wide substrate scope with high yield of the product for the synthesis of isoquinoline derivatives.

A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation Keywords:

Ru(II)/PEG-400 , Green synthesis , Homogeneous catalyst , Biodegradable solvent

A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation authors

Shrinivas L. Nakkalwar

Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India

Hanmant M. Kasralikar

Department of Chemistry, Shri Muktanand Mahavidyalaya, Gangapur,Dist. Aurangabad MS, India

Nitish S. Kaminwar

Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India

Shivaji B. Patwari

Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India

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