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Title

N,N,N ,N -tetramethylethylene-diaminium-N,N -disulfonic acid chloride as a highly effective catalyst for the synthesis of 4H-pyrano[2, 3-c]pyrazoles, α-carbamatoalkyl-β-naphthols and α-amidoalkyl-β-naphthols

Year: 1399
COI: JR_AJGC-4-2_005
Language: EnglishView: 137
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Authors

Sharareh Ravanshad - Department of Chemistry, Payame Noor University, PO Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran
Hakimeh Asvar - Department of Chemistry, Payame Noor University, PO Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran
Fatemeh Fouladi - Department of Chemistry, Payame Noor University, PO Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran
Arezoo Pourkazemi - Department of Chemistry, Payame Noor University, PO Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran

Abstract:

In this work, N,N,N ,N -tetramethylethylene-diaminium-N,N -disulfonic acid chloride {[TMEDSA][Cl]2} has been utilized as a highly effective catalyst in order to promote the following organic transformations under green, solvent-free and mild conditions: (i) the synthesis of 4H-pyrano[2, 3-c]pyrazoles from aromatic aldehydes, 3-methyl-1-phenyl-2-pyrazolin-5-one and malononitrile, (ii) the preparation of α-carbamatoalkyl-β-naphthols from arylaldehydes, β-naphthol and alkyl carbamates, and (iii) the production of α-amidoalkyl-β-naphthols from arylaldehydes, β-naphthol and amides.

Keywords:

N , N , N -Tetramethylethylene-diaminium-N , N -disulfonic acid chloride {[TMEDSA][Cl]2} Sulfonic acid-functionalized ionic liquid 4H-Pyrano[2 , 3-c]pyrazole α-Carbamatoalkyl-β-naphthol α-Amidoalkyl-β-naphthol

Paper COI Code

This Paper COI Code is JR_AJGC-4-2_005. Also You can use the following address to link to this article. This link is permanent and is used as an article registration confirmation in the Civilica reference:

https://civilica.com/doc/1032142/

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Ravanshad, Sharareh and Asvar, Hakimeh and Fouladi, Fatemeh and Pourkazemi, Arezoo,1399,N,N,N ,N -tetramethylethylene-diaminium-N,N -disulfonic acid chloride as a highly effective catalyst for the synthesis of 4H-pyrano[2, 3-c]pyrazoles, α-carbamatoalkyl-β-naphthols and α-amidoalkyl-β-naphthols,https://civilica.com/doc/1032142

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