An optimization and characterization study on sodium ferrate production by electrochemical method

Publish Year: 1398
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:

JR_JMATPR-7-4_001

تاریخ نمایه سازی: 9 مرداد 1400

Abstract:

Current efficiency and energy consumption are two important factors in sodium ferrate synthesis. In this article, sodium ferrate was produced by the electrochemical method and the effects of different synthesized parameters such as applied current density, sodium hydroxide concentration and temperature on current efficiency and energy consumption have been studied. Decomposition of sodium ferrate, anode passivation and deviations in anodic and cathodic reaction rates with time have been tested by weight loss test, potentiodynamic polarization, and UV-visible spectroscopy, respectively. Also, the impact of each one on current efficiency and its consequence on energy consumption rate were studied. The results showed that the optimum conditions were ۳.۹۴ mA/cm۲, ۱۶ M NaOH and ۵۰ oC for applied current density, sodium hydroxide concentration, and temperature, respectively. In this situation, the current efficiency was calculated as ۹۱.۷% and the energy consumption reached ۱.۹۱ kW.h/kg. Keywords: Electrochemical method; Sodium ferrate; Alkaline solution; Current efficiency; Energy consumption.

Authors

Sina Samimi-sedeh

Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran

Ehsan Saebnoori

Islamic Azad University- Najafabad Branch

Ali Hassanzadeh

Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran