The study of the modified silica by different metal ions in diastereoselectivity of Diels-Alder reaction

A mild procedure for the diastereoselective Diels-Alder reaction of methyl acrylate and cyclopentadiene was performed using modified silica with different concentrations of metal ions as Lewis acid support. According to the results, among the tested metal ions, cadmium ion supported on the silica was the best diastereoselective catalyst in this reaction.

Keywords:

Diels-Alder reaction , Silica gel , diastereoselective cycloaddition , methyl acrylates , Cyclopentadiene

Authors

G. Mohammadi Ziarani

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

Soheila Afsharnia

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

alireza badiei

School of Chemistry, College of Science, University of Tehran, Tehran, Iran

parisa Gholamzadeh

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

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https://civilica.com/doc/1383315

شناسه ملی سند علمی:

JR_JAOC-1-4_005

تاریخ نمایه سازی: 3 بهمن 1400

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Mohammadi Ziarani, G. and Afsharnia, Soheila and badiei, alireza and Gholamzadeh, parisa,1400,The study of the modified silica by different metal ions in diastereoselectivity of Diels-Alder reaction,https://civilica.com/doc/1383315

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Type of center: دانشگاه دولتی

Paper count: 11,262

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