THE EFFECT OF VOLATILE MATTER OF NON-COKING COAL ON THE REDUCTION OF IRON OXIDE AT NON-ISOTHERMAL CONDITION
Publish Year: 1394
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_IJMSEI-12-3_007
تاریخ نمایه سازی: 26 مرداد 1402
Abstract:
The volatile matter of non-coking coal was used for the reduction of hematite in argon atmosphere at nonisothermal condition. A thermal gravimeter furnace enable to use an ۸۰ mm-height crucible was designed for the
experiments to measure the weight changes of about ۱۰ grams samples. A two-layered array of coal and alumina and
four-layered array of iron oxide, alumina, coal and alumina was used for the devolatilization and reduction
experiments, respectively. The net effect of volatile reduction of Fe
۲O۳was determined and it was observe that ۴۵%
reduction has been achieved. Three distinct regions were recognized on the reduction curve. The reduction of hematite
to magnetite could be completely distinguished from the two other regions on the reduction curve. At ۶۰۰-۹۵۰°C, the
reduction was accelerated. ۶۳% of volatile matter resulted in ۲۵% of total reduction before ۶۰۰°C while the remaining
volatile matter contributed to ۷۵% of the total reduction. From the reduction rate diagram, the stepwise reduction of
the iron oxides could be concluded. The partial overlap of the reduction steps were identified through the XRD studies.
The starting temperature of magnetite and wüstite reduction were determined at about ۵۸۵°C and at ۸۱۰°C,
respectively.
Keywords:
Authors
M. H. Hemmati
Department of Metallurgical Engineering, Iron and Steel Research Center, Ferdowsi University of Mashhad, Iran.
J. Vahdati Khaki
Department of Metallurgical Engineering, Iron and Steel Research Center, Ferdowsi University of Mashhad, Iran.
A. Zabett
Department of Metallurgical Engineering, Ferdowsi University of Mashhad, Iran.