Tonsil Clay as a Green Catalyst for Rapid and Efficient Reduction of Aldehydes and Ketones with NaBH۳CN

Reduction of aldehydes and ketones to the corresponding alcohols in the presence of sodium cyanoborohdride as reductive agent and Tonsil clay as catalyst under solvent free conditions was investigated. Tonsil (catalyst) decreased the reduction time of each aldehyde and ketone to proportional alcohols in comparison with their reduction in the absence of catalyst with high degree purity of alcohols. Reduction reactions were carried out in solvent free condition in less than ۱۵ minutes at room temperature. All obtained alcohols from reduction of related carbonyl compounds were detected by FT-IR and ۱H/۱۳C NMR spectra.

Keywords:

Sodium cyanoborohydride , Tonsil clay , reduction , Aldehyde , Ketone , Alcohols , Green chemistry

Authors

Ali Danesh

Department of Chemistry, Ahar branch, Islamic Azad University, Ahar, Iran

Masomeh Aghazadeh

Department of Chemistry, Maku Branch, Islamic Azad University, Maku, Iran

Mohammad Jalilzadeh Hedayati

Department of Chemistry, Ahar branch, Islamic Azad University, Ahar, Iran

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https://civilica.com/doc/1766177

شناسه ملی سند علمی:

JR_ORGC-5-2_001

تاریخ نمایه سازی: 3 مهر 1402

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Danesh, Ali and Aghazadeh, Masomeh and Jalilzadeh Hedayati, Mohammad,1398,Tonsil Clay as a Green Catalyst for Rapid and Efficient Reduction of Aldehydes and Ketones with NaBH۳CN,https://civilica.com/doc/1766177

Scientometrics

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Ranking of Islamic Azad University of Ahar

Type of center: Azad University

Paper count: 2,911

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