Studying of Catalyst Deactivation in a Commercial Hydrocracking Process (ISOMAX)
Publish Year: 1390
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_JPSTR-1-1_006
تاریخ نمایه سازی: 29 آذر 1402
Abstract:
Catalyst deactivation is usually indispensable, although the rate at which it occurs varies greatly. At first, this article discusses the causes of deactivation in a commercial hydrocracking unit called Isomax. Then, a ۵-lump kinetic model including catalyst decay function for hydrocracking of vacuum gas oil in a commercial plant is proposed. The model considers vacuum gas oil (VGO) having boiling point higher than ۳۸۰oC (۳۸۰+°C), diesel (۲۶۰-۳۸۰°C), kerosene (۱۵۰-۲۶۰°C), naphtha (IBP:۱۵۰°C), and gas as products. By using selective catalyst decay function in the kinetic model, the effect of the catalyst deactivation on the yield of products over time is studied. The prediction of the model during ۱.۵ years is in good agreement with the actual commercial data. The average absolute deviation (AAD%) of the model for the strategic products like naphtha, kerosene and diesel are about ۱.۷۸۴%, ۱.۹۸۳% and ۱.۹۷۱%, respectively. Also it is observed that the estimated parameters are consistent with the reported characteristics of amorphous catalysts.
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Authors
Mahdi Rashidzadeh
Catalysis Research Center, Research Institute of Petroleum Industry, Tehran, Iran
A. Ahmad
Faculty of Chemical and Natural Resources Engineering, Universiti Teknologi Malaysia, UTM Skudai, Johor Bahru, ۸۱۳۱۰ Malaysia
S. Sadighi
Faculty of Chemical and Natural Resources Engineering, Universiti Teknologi Malaysia, UTM Skudai, Johor Bahru, ۸۱۳۱۰ Malaysia
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