Effect of Solution Dielectric Constant on the Preparation of Gas Diffusion Electrode Reaction Layer for the Oxygen Reduction Reaction
Publish place: Iranian Journal of Hydrogen & Fuel، Vol: 10، Issue: 2
Publish Year: 1402
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_IJHFC-10-2_001
تاریخ نمایه سازی: 28 اسفند 1402
Abstract:
This study explored the impact of solvent dielectric constant on the catalyst layer of proton exchange membrane fuel cell (PEMFC) cathodes during the oxygen reduction reaction. Electrochemical analyses were conducted at ۲۵ºC in ۲.۰ M H۲SO۴ on electrodes that had been prepared with the same Nafion and Pt loadings, but different solvent dielectric constants for ink preparation of the catalyst layer. A Nafion loading of ۰.۵ mg cm-۲ and Pt loading of ۱ mg cm-۲ were employed for all electrodes. The findings of the research revealed that the dielectric constant of the ink utilized for preparing the gas diffusion electrode reaction layer has an impact on the electrode's performance for the oxygen reduction reaction. This effect was evident in both the kinetics parameters linked to the oxygen reduction reaction and the physical characteristics of the electrode surface. In the preparation of the reaction layer, an optimal electrode performance result of ۴.۲ was achieved in relation to the dielectric constant.
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Authors
Rasol Abdullah Mirzaie
Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran
Hussein Gharibi
Department of Chemistry, Faculty of Science, Tarbiat Modares University, P.O.Box ۱۴۱۱۵-۱۷۵, Tehran, Iran
Elaheh Lohrasbi
Department of Chemistry, Faculty of Science, Tarbiat Modares University (TMU), Tehran, P.O. Box ۱۴۱۱۵-۱۷۵, Iran
Mehdi Kheirmand
Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, Iran
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