Kinetic investigation of methane hydrate in the presence of Imidazolium Based Ionic Liquid solutions
Publish place: 02nd National Iranian Conference on Gas Hydrate
Publish Year: 1392
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
NICGH02_034
تاریخ نمایه سازی: 25 شهریور 1392
Abstract:
Methane hydrate formation experiments in the presence of the various imidazolilium based ionic liquid solutions with 0.5wt% concentration including 1-buthyl-3-methylimidazolium methyl sulfate ([BMIM][MeSO4]) , 1-ethyl-3-methylimidazolium hydrogen sulfate ([EMIM][HSO4]), 1-ethyl-3-methylimidazolium ethyl sulfate ([EMIM][EtSO4]), 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) and 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ([OH-EMIM][BF4]) were conducted in a high pressure reactor at the same temperature. The induction time, gas consumption and temperature were measured.The results of experiments were indicated that [EMIM][EtSO4] and [BMIM][MeSO4] had the kinetic inhibiton effects meanwhile the other ionic liquids could be able to apply as the kinetic promoters
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Authors
M. Zare
Department of Chemical Engineering, Tarbiat Modares University, P.O. Box: ۱۴۱۱۵-۱۴۳, Tehran, Iran
A. Haghtalab
Department of Chemical Engineering, Tarbiat Modares University, P.O. Box: ۱۴۱۱۵-۱۴۳, Tehran, Iran
A. N. Ahmadi
Center of chemistry and petrochemical, Research Institute of Petroleum Industry, Tehran, Iran
K. Nazari
Center of chemistry and petrochemical, Research Institute of Petroleum Industry, Tehran, Iran
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