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The Comparison between Initial Charge, Shot and Modified Shot Processes and Their Effects on Macrostructure of Particles in Emulsion Copolymerization of Styrene- Butadiene- Acrylic Acid

Publish Year: 1383
Type: Conference paper
Language: English
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NICEC09_157

Index date: 3 April 2007

The Comparison between Initial Charge, Shot and Modified Shot Processes and Their Effects on Macrostructure of Particles in Emulsion Copolymerization of Styrene- Butadiene- Acrylic Acid abstract

Carboxylated styrene- butadiene latexes with 30% solid content were prepared by emulsion copolymerization technique with initial charge and shot- addition methods. The distribution of carboxylic groups in different locations of latex system i.e. interior and surface of particles and aqueous phase during polymerization reaction was studied by conductometric back titration method (Hen method). The obtained results from shot process show that addition of acrylic acid with some water in interval III of emulsion polymerization will decrease the amount of surface bound carboxylic acids relative to initial charge method. So the process of shot- addition was modified by addition of styrene, emulsifier and initiator accompanied with acrylic acid and water in conversions above 80% in the second stage. The analysis of the obtained latex shows that the amount of surface bound acid was raised from 58% for initial charge method to 72% for this modified technique.

The Comparison between Initial Charge, Shot and Modified Shot Processes and Their Effects on Macrostructure of Particles in Emulsion Copolymerization of Styrene- Butadiene- Acrylic Acid Keywords:

The Comparison between Initial Charge, Shot and Modified Shot Processes and Their Effects on Macrostructure of Particles in Emulsion Copolymerization of Styrene- Butadiene- Acrylic Acid authors

AliReza Mahdavian

Polymer Science Department, Iran Polymer & Petrochemical Institute, Tehran, Iran

Mahdi Abdollahi

Polymer Science Department, Iran Polymer & Petrochemical Institute, , Tehran, Iran

Foroud Abbasi Sourki

Polymer Science Department, Iran Polymer & Petrochemical Institute, Tehran, Iran

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G. W. Ceska, J. Appl. Polym. Sci. 18 (1974). G. ...
K. Sakota, T. Okaya, J. App. Polym. Sci. 20 (1976). ...
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