Preparation nanostructured materials by sol–gel crosslinking process in present N, N-dimethyl amino pyridinium ionic liquid as a catalysis
Publish place: Journal of Communications In Catalysis، Vol: 1، Issue: 1
Publish Year: 1396
نوع سند: مقاله ژورنالی
زبان: English
View: 484
This Paper With 11 Page And PDF Format Ready To Download
- Certificate
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
JR_CIC-1-1_004
تاریخ نمایه سازی: 26 فروردین 1397
Abstract:
Silica porous materials with use of the some of ionic liquids (ILs) based N, N-dimethyl aminopyridinium cation (DMAP) with high thermal stability was prepared.First according to a proper sol-gel method, various RTILs with anions such as= Br, BF4 as a new kind of recyclable templates in present of trimethoxy silane (TMOS) as the sol-gel precursor and deionized water were employed. Then ILs was removed from the silica matrix by calcination method.The resulting gels were characterized by using thermogravimetric analysis, infrared spectroscopy. The calcined gels were analyzed using scanning electron microscopy and X-ray diffraction. In the continuous, reaction was fallowed under acidic conditions at temperature above the melting point of the functional IL such as; 2–ethoxyethyl-4-(N, N-dimethyl amino) pyridinum tetrafluoroborate with larger hydrophilic polar region in a so-called nanocasting sol-gel technique, those silica nanostructured materials with highly ordered monolithic was obtained.
Keywords:
Sol-Gel process , N , N-dimethyl amino pyridinium ionic liquid , Nanostructured material , Silica , Ionogel
Authors
Hanie Musazade
Organic Chemistry Departement, Chemistry Faculty, Tabriz University