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A comparative study of catalytic properties of ZnO and FeZnO nanoparticles on oxidation of Benzylic alcohols: Influence of doped metal

Publish Year: 1394
Type: Journal paper
Language: English
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Document National Code:

JR_ICC-3-3_003

Index date: 23 July 2018

A comparative study of catalytic properties of ZnO and FeZnO nanoparticles on oxidation of Benzylic alcohols: Influence of doped metal abstract

Novel nano-catalysts (Nano ZnO and Fe doped ZnO (Fe(0.1)Zn(0.99)O) were synthesized by coprecipitationmethod in aqueous solution as new nanocatalysts and characterized by commontechniques as FTIR, XRD, SEM and UVD. The size of particles obtained from XRD data is 27and 16 nanometers for ZnO and Fresno respectively. Influences of doped Fe on ZnO catalyticproperties in oxidation of Benzylic alcohols were studied. The oxidation was carried out undermild and green conditions as solvent free, at room temperature and with H2O2. The results show,that FeZnO is better than ZnO as nanocatalyst in oxidation reaction. The rate, of %conversionand %selectivity of reaction is improved in the presence of Fe atoms than ZnO only. The mainproduct of oxidation reactions is Benzaldehyde and/or its derivatives.

A comparative study of catalytic properties of ZnO and FeZnO nanoparticles on oxidation of Benzylic alcohols: Influence of doped metal Keywords:

A comparative study of catalytic properties of ZnO and FeZnO nanoparticles on oxidation of Benzylic alcohols: Influence of doped metal authors

Hamid Reza Mardani

Department of Chemistry, Payame Noor University, P.O. BOX ۱۹۳۹۵-۴۶۹۷ Tehran, Iran

Mehdi Forouzani

Department of Chemistry, Payame Noor University, P.O. BOX ۱۹۳۹۵-۴۶۹۷ Tehran, Iran

Mitra Ziari

Department of Chemistry, Payame Noor University, P.O. BOX ۱۹۳۹۵-۴۶۹۷ Tehran, Iran

Azim Malekzadeh

Department of Chemistry, Damghan University, Iran