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Title

Conductance and FTIR Spectroscopic Study of Triple-ion Formation of Tetrabutylphosphonium Methanesulfonate in Methylamine Solution

Year: 1398
COI: JR_CHM-4-1_005
Language: EnglishView: 141
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Authors

Samir Das - Department of Chemistry, University of North Bengal, Darjeeling-۷۳۴۰۱۳, India
Deepak Ekka - Department of Chemistry, Cooch Behar Panchanan Barma University, Coochbehar-۷۳۴۰۰۱, India
Mahendra Roy - Department of Chemistry, University of North Bengal, Darjeeling-۷۳۴۰۱۳, India

Abstract:

Triple-ion formation of tetrabutylphosphonium methanesulfonate [Bu4PCH3SO3] in methylamine solution has been reported quantitatively by conductometric study, and the observation has evident from the qualitative analysis of FT-IR spectroscopy. The ionic liquid exists as triple-ion state in low dielectric constant solution (methylamine solution having εr<10). Thus, the conductance data have been analysized using the fuoss-kraus theory of triple-ion formation. After that, the results have been discussed in terms of driving forces i.e., H-bond formation, dipole-dipole interactions, and structural aspect (functional group) of the ionic liquid and methylamine molecules. Shifting of the stretching frequency of functional group of the solvent in presence and absence of the ionic liquid has been taken into account in FTIR spectroscopic study, and then the solvation consequence has been manifest by the change of the intensity.

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This Paper COI Code is JR_CHM-4-1_005. Also You can use the following address to link to this article. This link is permanent and is used as an article registration confirmation in the Civilica reference:

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Das, Samir and Ekka, Deepak and Roy, Mahendra,1398,Conductance and FTIR Spectroscopic Study of Triple-ion Formation of Tetrabutylphosphonium Methanesulfonate in Methylamine Solution,https://civilica.com/doc/941824

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