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Effect of CQDs on permeability and hydrophilicity of PAN TFN membranes

Publish Year: 1401
Type: Conference paper
Language: English
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IAAMM02_012

Index date: 7 August 2022

Effect of CQDs on permeability and hydrophilicity of PAN TFN membranes abstract

To investigate the effect of carbon quantum dots (CQDs) nanoparticles on the permeability andhydrophilicity of poly acrylonitrilepolyacrylonitrile (PAN) thin thin-film nanocomposite (TFN)membranes, in this paper, carbon quantum dots (CQDs) were synthesized by hydrothermal methodand embedded as dispersed phase in the active poly-amide (PA) layer of the TFN thin-filmnanocomposite membrane by interfacial polymerization. The CQDs nanoparticles were analyzed byHR-TEM, FTIR, UV Reflectance and UV Spectroscopy tests. Also, fabricated membranes werecharacterized by contact angle and permeability tests. HR-TEM results showed that the synthesizednanoparticles are 1 to 2 nanometers in size and spherical. The presence of hydroxyl and carbonylfunctional groups on the surface of the nanoparticles, which was determined by FTIR analysis,confirmed the hydrophilicity of CQDs nanoparticles. The results of the contact angle test showed thatwith increasing the concentration of CQDs nanoparticles, the contact angle of the water droplet withthe membrane surface decreased, which in the TFN-CQDs10% wt sample compared to the neat thinfilmcomposite (TFC) sample, the contact angle decreased by 9 degrees. Also, The the permeabilityvalue increased from 21.25 L/m2.h LMH for the TFC sample to 48.75 L/m2.h LMH for the TFNCQDs10% wt sample. Therefore, CQDs nanoparticles had a positive effect on the permeability andhydrophilicity of fabricated TFN membranes.

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Effect of CQDs on permeability and hydrophilicity of PAN TFN membranes authors

Ebrahim Yazdanmanesh

Membrane Research Laboratory, Caspian Faculty of Engineering, College of Engineering, University ofTehran;

MohammadAli Aroon

Membrane Research Laboratory, Caspian Faculty of Engineering, College of Engineering, University ofTehran;

Elham Abdollahzadeh Sharghi

Environmental Group, Department of Energy, Materials and Energy Research Center;