COMPARATIVE MAGNETIC AND PHOTOCATALYTIC PROPERTIES OF COPRECIPITATED ZINC FERRITE NANOPARTICLES BEFORE AND AFTER CALCINATION

In this work, the effects of co-precipitation temperature and post calcination on the magnetic properties and photocatalytic activities of ZnFe۲O۴ nanoparticles were investigated. The structure, magnetic and optical properties of zinc ferrite nanoparticles were characterized by X-ray diffraction (XRD), vibrating sample magnetometry and UV–Vis spectrophotometry techniques.  The XRD results showed that the coprecipitated as well as calcined nanoparticles are single phase with partially inverse spinel structures. The magnetization and band gap decreased with the increasing of co-precipitation temperature through the increasing of the crystallite size. However, the post calcination at ۵۰۰ °C was more effective on the decreasing of magnetization and band gap. Furthermore, photocatalytic activity of zinc ferrite nanoparticles was studied by the degradation of methyl orange under UV-light irradiation. Compare with the coprecipitated ZnFe۲O۴ nanoparticles with ۵% degradation of methyl orange after ۵ h UV-light light radiation, the calcined ZnFe۲O۴ nanoparticles exhibited a better photocatalytic activity with ۲۰% degradation.

Keywords:

Zinc ferrite , Coprecipitation , Band gap , Photocatalytic activity