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Synthesis and characterization of chiral nano-poly [(±)-2-sec-butylaniline] via FeCl3.6H2O as an oxidant and investigation of itsapplication in the first chiral solar cell

Publish Year: 1400
Type: Conference paper
Language: English
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ASCCE01_019

Index date: 15 December 2024

Synthesis and characterization of chiral nano-poly [(±)-2-sec-butylaniline] via FeCl3.6H2O as an oxidant and investigation of itsapplication in the first chiral solar cell abstract

A chiral derivative of polyaniline, poly [(±)-2-sec-butyl aniline] (PSBA), was successfully synthesized.The polymerization is carried out by oxidative polymerization of (±)-2-sec-butyl aniline in the presenceof FeCl3.6H2O under both solid (solvent-free) and solution state conditions. Several techniques used tocharacterize the polymers, such as; ultraviolet-visible (UV-vis) spectroscopy, Fourier-transforminfrared (FT-IR), Dr. Blade's method was used to construct polymer solar cells with a structure such asFTO/TiO2/1/Al, FTO/TiO2/2/Al, FTO/TiO2/3/Al and FTO/TiO2/4/Al. The PCE (power conversionefficiency) of the FTO/TiO2/1/Al, FTO/TiO2/2/Al, FTO/TiO2/3/Al and FTO/TiO2/4/Al samples were0.36, 0.21, 0.32 and 0.16%, respectively. The advantages of our solar cell are simple structure (singlelayer), easy to fabricate, fewer fabrication costs, green synthesis condition, and the high stability of theresulted cells.

Synthesis and characterization of chiral nano-poly [(±)-2-sec-butylaniline] via FeCl3.6H2O as an oxidant and investigation of itsapplication in the first chiral solar cell Keywords:

Synthesis and characterization of chiral nano-poly [(±)-2-sec-butylaniline] via FeCl3.6H2O as an oxidant and investigation of itsapplication in the first chiral solar cell authors

Farideh Paymozd

Organic and Polymer Research Laboratory, Department of Chemistry, Faculty of Science

Ali Reza Modarresi-Alam

Organic and Polymer Research Laboratory, Department of Chemistry, Faculty of Science۲- Renewable Energies Research Institute, University of Sistan and Baluchestan, Zahedan, Iran

Hamideh Saravani

Renewable Energies Research Institute, University of Sistan and Baluchestan, Zahedan, Iran۳- Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran