Fe3O4@SiO2-SO3H nanoparticles as a magnetically green catalyst for the synthesis of spirooxindoles under microwave irradiation
Publish place: The third national conference on new technologies in the chemical, petrochemical and Iran Nanotechnology
Publish Year: 1395
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
TCPCO03_144
تاریخ نمایه سازی: 16 شهریور 1395
Abstract:
Sulfuric acid has been successfully attached to the core–shell structural (Fe3O4@SiO2) nanoparticles, and characterized by Powder X-ray Diffraction, Vibrating Sample Magnetometer, Scanning Electronic Microscope, Transmission Electron Microscope, Energy Dispersive X-ray, Thermal Gravimetric Analyser and Fourier transform infrared spectroscopy. The prepared nanoparticles employed as a heterogeneous catalyst in the synthesis of spirooxindoles derivatives in one-pot four component reactions of isatin, dimedone, hydrazine hydrate and ethyl acetoacetate under microwave irradiation. Fe3O4@SiO2-SO3H nanoparticles showed high catalytic activity in mild reaction conditions and excellent yields of products in short reaction times. Also, this nano-catalyst can be easily recovered by a magnet and reused for subsequent reactions for at least five times without noticeable loss in catalytic activity
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Authors
F Alemi-Tameh
Department of Chemistry, Science and Research branch, Islamic Azad University, Tehran, Iran
J Safaei-Ghomi
Department of Organic Chemistry, Faculty of Chemistry, University of Kashan