On the Evaluation of Dieterici Model Via The Study of Bulk Modulus and Tait-Marnagan Regularity of Associating Fluids
Publish place: 20th Iranian Conference on the Chemistry of Physics
Publish Year: 1396
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ISPTC20_229
تاریخ نمایه سازی: 2 تیر 1397
Abstract:
Equations of State (EOS) are major tools for correlation and prediction of thermodynamic properties offluids, therefore a large number of publications deal with their development or improvement.In 1899, Dietericiproposed an alternative theoretically based EOS involving an exponential term att ZZ Z repe . There are some advantagesin this model, such as a more realistic critical compressibility factor (Z).In this paper, we calculate bulk modulus andstudy Tait-Marnaganregularity of associating fluids in order to evaluate the performance of equations of state (EOS)based on Dieterici model. The investigated EOSs are Dieterici (D), Dieterici-Carnahan-Starling (DCS) and Dieterici-Guggenheim (DG). Our studies show that the bulk modulus and the regularityare predicted well by EOSs for allsubstances.
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Authors
Mohsen Najafi
Nuclear Science and Technology Research Institute, AEOI, Tehran, Iran
Mahdi Darvishi
Department of Chemistry ,Payam Noor University , Iran