Synthesis of beta-zeolite for applying in the ring-opening reaction

Publish Year: 1396
نوع سند: مقاله کنفرانسی
زبان: English
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NZEOLITE04_040

تاریخ نمایه سازی: 11 شهریور 1397

Abstract:

Zeolites have a wide area of applications as catalyst, adsorbent and ion exchanger [1, 2]. Of the more than 200 known zeolite topologies with a framework code assigned by the Structure Commission of the International Zeolite Association [3]. Beta zeolite is one of the useful compounds that constitute the majority of the commercial zeolite catalyst production [4]. Zeolite Beta, with its intriguing framework architecture and 3-dimensional pore system, displays superior performance in refinery applications, environmental catalysis and a variety of organic reactions because of its vastly accessible pore volume, high adsorption capacity, strong acid sites and shape/size selectivity [5]. The opening of epoxides with alcohols is one of the important transformations for the synthesis of ß-alkoxy alcohols which are mainly used as valuable organic solvents, versatile synthons and intermediates [6]. In this report, the prepared heterogeneous acidic nanocatalyst has been applied in the ring opening of styrene oxide by alcohols under ambient temperature.

Authors

Mahsa Eskandarzade

Inorganic Nanostructures and Catalysts Research Lab., Chemistry & Chemical Engineering Research Center of Iran, Pajoohesh Blvd., km ۱۷,Karaj Hwy, Tehran ۱۴۹۶۸-۱۳۱۵۱, Iran

Aliakbar Tarlani

Inorganic Nanostructures and Catalysts Research Lab., Chemistry & Chemical Engineering Research Center of Iran, Pajoohesh Blvd., km ۱۷,Karaj Hwy, Tehran ۱۴۹۶۸-۱۳۱۵۱, Iran