Estimation of the Concentration of Diazinon Pesticide in Drinking Water Resources in Summer Areas of Mashhad, Iran

Background & Aims of the Study: Torqabeh and Shandiz are the two most well-knownareas among the varied summer areas of Mashhad. The climate of these areas is appropriatefor the development of agriculture and gardening and attracting tourists. Hence,maintaining the safety of drinking water is necessary in these areas. This study was carriedout to investigate the diazinon concentration in drinking water resources (groundwater) inthe summer areas of Mashhad city.Materials & Methods: Sixty water samples, with the volume of 250 ml, were gatheredfrom 10 wells and springs in the villages of Shandiz and Torqabeh in two seasons. Theliquid-liquid extraction was performed using dichloromethane solvent and theconcentrations were measured using High-Performance Liquid Chromatography (HPLC)system (KNAUER model) which was equipped with UV detector. The data were analyzedby SPSS software (Version 16). A probability level of P<0.05 was considered asstatistically significant. The data were compared to the standards of WHO and EPA.Results: A linear relationship between concentration and peak area was obtained within therange of 0.05 to 2 ppb with R2 (Correlation coefficient) values greater than 0.99.Recoveries for spiked water samples with six diazinon standards in 0.05 to 2 ranged from79.63 to 110.90% (with an average of 92.80±12.12). The results indicated that diazinonwasn’t detectable in the springs of the studied areas while the wells of Torqabeh (with anaverage concentration of 0.82 μg/l) were contaminated more than the wells of Shandiz(with an average concentration of 0.48 μg/l), measured by HPLC. The maximum andminimum of contamination were observed in the villages of Veyrani1 and Nochah,respectively, measured by HPLC.Conclusions: The concentration of diazinon in Shandiz and Torqabeh areas was higherthan standard limits of WHO (0.1 μg/l) and EPA (9×10-6 mg/l). Also, the averageconcentration of diazinon in Torqabeh (0.61 μg/l) was higher than that in Shandiz (0.48μg/l) and the contamination in wells was observed to be more (0.59 μg/l) than springs.

Keywords:

Diazinon , pesticide , HPLC , water resources , summer areas , Mashhad