Modeling the Solubility of 1,1,1,2-Tetrafluoroethane (R134a) in RoomTemperature Ionic Liquids using Generic-van der Waals and Generic-Redlich-Kwong Equations of state
Publish place: Fifth National Conference on New Research on Chemistry, Chemical Engineering and Petroleum
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
NRCP05_001
تاریخ نمایه سازی: 18 مرداد 1398
Abstract:
In this paper we have examined modeling of 1,1,1,2-Tetrafluoroethane (R134a) solubility in TenRoom Temperature Ionic Liquids (RTILs) based on Generic-Van der Waals (GVDW) and Generic-Redlich-Kwong (GRK) Equations of state (EOSs) and also have compared deviations with each other.Experimental data represent a high correlation with the Present equation of states. It is also concludedthat the absolute average deviation (AAD%) is less than 1% for each system that illustrates highaccuracy and efficiency of the mentioned Present equation of states. Henry s law constant and some thermodynamic properties such as enthalpy (ΔH? ) and entropy (Δ?? ) in infinite dilution are calculated
Keywords:
1 , 1 , 1 , 2-Tetrafluoroethane , Room Temperature Ionic Liquids , modeling , Equation ofstate , Henry s law constant , enthalpy and entropy in infinite dilution
Authors
Amir Hossein Saali
Department of Chemical Engineering, Science and Research Branch, Islamic Azad University,Tehran, Iran
Hossein Sakhaeinia
Department of Chemical Engineering, Central Tehran Branch, Islamic Azad University, Tehran,Iran.
Mohammad Shokouhi
Research Institute of Petroleum Industry (RIPI), Gas Research Division, P.O. Box ۱۴۶۶۵-۱۳۷,Tehran, Iran