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Title

Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands

Year: 1398
COI: JR_CHM-3-5_002
Language: EnglishView: 140
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Authors

Aliakbar Dehno Khalaji - Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
Ensieh Shahsavani - Ph.D Educated, Department of Chemistry,Payamenoor University, Mashhad, Iran
Michal Dusek - Institute of Physic ASCR, v. v. i., Na Slovance ۲, ۱۸۲ ۲۱, Prague, Czech Republic
Monika Kucerakova - Institute of Physic ASCR, v. v. i., Na Slovance ۲, ۱۸۲ ۲۱, Prague, Czech Republic

Abstract:

In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.

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Paper COI Code

This Paper COI Code is JR_CHM-3-5_002. Also You can use the following address to link to this article. This link is permanent and is used as an article registration confirmation in the Civilica reference:

https://civilica.com/doc/941801/

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Dehno Khalaji, Aliakbar and Shahsavani, Ensieh and Dusek, Michal and Kucerakova, Monika,1398,Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands,https://civilica.com/doc/941801

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