Analytical Methods: Electrochemical azido-selenenylation of some olefins by cyclic voltammetry and controlled-potential coulometry
Publish Year: 1398
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_AMECJ-1-1_008
تاریخ نمایه سازی: 3 اسفند 1398
Abstract:
Electrochemical azido-phenylselenenylation of some olefins was studied with the oxidation of diphenyl diselenide in the presence of some olefins and sodium azide in dimethyl formamide containing tetra butyl ammonium perchlorate as supporting electrolyte in an H-type cell. The electrochemical oxidation of the mixture of (PhSe)2, olefins, and NaN3 was studied by cyclic voltammetry and controlled-potential coulometry. Anti product can be obtained with Markovnikov orientation. This product was characterized .by 1H, 13C NMR, and IR spectroscopy
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Authors
ahmad rouhollahi
Chemistry Department, Faculty of Science, K.N. Toosi University of Technology, Tehran ۱۵۴۱۸, Iran.
zeenat asghari
Chemistry Department, Faculty of Science, K.N. Toosi University of Technology, Tehran ۱۵۴۱۸, Iran.
barahman movassagh
Chemistry Department, Faculty of Science, K.N. Toosi University of Technology, Tehran ۱۵۴۱۸, Iran.