A novel MCM-41 supported by metal complexes such a cobalt and Mangenes for oxidation of organic compound

Publish Year: 1387
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:

ZEOLITE01_178

تاریخ نمایه سازی: 30 دی 1387

Abstract:

The modification of the internal pore surface of mesoporous MCM-41 with 3-aminopropyl yielded amine group functionalized MCM-41. Cobalt (II) and Mangenes (II) acetylacetonate were grafied onto the functional MCM-41 via coordination of the nitrogen donor legend.The metal ion complex functionalized mesoporous materials were characterized by powder X-ray diffraction (XRD), IR and GC-mass methods. This work reports the results of 2-Brombenzylalcohol and similar compounds oxidation in the liquid phase, over Cobalt acetylacetonate anchored onto MCM-41.

Authors

Abdollah Fallah-Shojaie

Department of chemistry, Faculty of science, Guilan University, Rasht, Iran

Mahboubeh Delavar-rafiee

Department of chemistry, Faculty of science, Guilan University, Rasht, Iran