Synthesis and Characterization of Magnetic Poly[St-co-CMS] Nanocomposites by ATRP Method
Publish place: 26th Iranian Seminar on Organic Chemistry
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ISOC26_107
تاریخ نمایه سازی: 2 شهریور 1398
Abstract:
Polymer-based magnetic nanocomposites have gained an increasing attention because of theirpotential applications [1,2]. A variety of functional polymers such as polystyrene have beenused for the preparation of nanocomposites. This polymer is generally obtained via copolymerizationof styrene (St) and chloromethyl styrene (CMS) monomers by using one of thecontrolled radical polymerization methods such as atom transfer radical polymerization(ATRP) [3]. In this study some poly[St-co-CMS]/Fe3O4 nanocomposites in different St/CMSratios are synthesized through ATRP method starting from styrene/CMS monomers and magnetite-containing benzyl chloride initiator. In this rout, MNP s initially link to the polymerizationinitiator. The copolymers synthesized are thoroughly charecterised by Fourier transforminfraredspectroscopy (FT-IR), thermogravimetric analysis (TGA), field emission-scanningelectron microscopy (FE-SEM), X-ray diffraction (XRD), and vibrating sample magnetometry(VSM) techniques.
Authors
Elham Naeemikhah
School of Chemistry, Damghan University, Damghan, Iran
Hossein Behniafar
School of Chemistry, Damghan University, Damghan, Iran
Aziz Ahmadi-Khaneghah
School of Chemistry, Damghan University, Damghan, Iran